Pigments from Pasargadae and Persepolis in the Metropolitan Museum of Art (NY): recent scientific investigations on four paper squeezes

Atefeh Shekofteh; Alexander Nagel; Omid Oudbashi

doi:10.14568/cp35708

Autores

Atefeh Shekofteh Department of Scientific Research, Metropolitan Museum of Art, 1000 Fifth Ave, NY 10028, USA https://orcid.org/0000-0003-0664-8476
Alexander Nagel Department of Art History, State University of New York, FIT, 227 West 27th Street, NY 10001, USA https://orcid.org/0000-0002-0430-885X
Omid Oudbashi Department of Conservation, University of Gothenburg, Medicinaregatan 7 B, 41390, Sweden https://orcid.org/0000-0002-7984-8199

DOI:

https://doi.org/10.14568/cp35708

Palavras-chave:

Pasárgada, Persépolis, Pigmentos, Lazurite, Hematite, Goetite

Resumo

Os moldes em papel retirados de fragmentos arquitetónicos de Pasárgada e Persépolis do Metropolitan Museum of Art (MMA) de Nova Iorque foram caracterizados através de investigação microscópica, técnicas de imagem e análises químicas e moleculares. O estudo centrou-se nos pigmentos de (1) um relevo de uma orelha antropomórfica de um fragmento do Palácio P, (2) um fragmento de uma roseta da coroa de um Lamassu da Porta R (“Casa da Porta”), ambos em Pasárgada; (3) um machado de pedra de uma delegação representada na fachada norte da Apadana, e (4) um bloco de pedra com uma inscrição hebraica de uma das molduras de porta ou janela do Tachara, Persépolis. As análises confirmaram pigmentos vermelhos já identificados em estudos anteriores e revelaram novas evidências de lazurite como pigmento azul e magnetite como pigmento negro. Os resultados podem ajudar a construir outros aspetos de contextos específicos de policromia antiga em Pasárgada e Persépolis.

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Referências

Stodulski, L.; E. Farrell; R. Newman, ‘Identification of ancient Persian pigments from Persepolis and Pasargadae’, Studies in Conservation 29(3) (1984) 143-154, https://doi.org/10.2307/1506017.

Nagel, A., Color and meaning in the art of Achaemenid Persia, Cambridge University Press, Cambridge (2023).

Ernst Herzfeld Papers, Smithsonian Institution, NMAA, Gift of Ernst Herzfeld (1946).

Nagel, A., R. Woody, ‘Excavations in an archive. An update on the Ernst Herzfeld online resources at the Freer|Sackler in Washington DC’, in A hundred years of excavations in Samarra, ed. J. Gonnella, Reichert, Wiesbaden (2014) 18-27.

Root, M. C., ‘The Herzfeld archive of The Metropolitan Museum of Art’, Metropolitan Museum Journal 11 (1976) 119-124.

Nagel, A., ‘Preserving the Achaemenid Persian legacy: aspects of conservation, technology, polychromy, and material culture in Persepolis’, in The art of empire in Achaemenid Persia: studies in honour of Margaret Cool Root, eds. E. Dusinberre, M. Garrison & W. Henkelman, Netherlands Institute for the Near East (NINO), Leiden (2020) 113-136.

Booth, C., Excavating paper squeezes: identifying the value of nineteenth and early twentieth century squeezes of ancient Egyptian monuments, through the collections of seven UK archives, PhD dissertation, Department of Classics, Ancient History and Archaeology, University of Birmingham, Birmingham (2018), https://etheses.bham.ac.uk/id/eprint/8715/ (accessed 2024-05-07).

Van de Ven, A., ‘The biography of the lateran squeezes: the curation of archaeological knowledge through hands-on replication’, Museum History Journal 16(2) (2023) 119-140, https://doi.org/10.1080/19369816.2023.2187947.

Burman, A., ‘Paint pigment on epigraphic squeezes: a case-study from the Etruscological collections of Olof August Danielsson’, Etruscan and Italic Studies 26(2) (2023) 44-63, https://doi.org/10.1515/etst-2022-0017.

Calmeyer, P., ‘Figürliche Fragmente aus Pasargadae nach Zeichnungen E. Herzfelds’, Archäologische Mitteilungen aus Iran N.S. 14 (1981) 27-44.

Herzfeld, E., ‘Bericht über die Ausgrabungen von Pasagardae 1928’, Archäologische Mitteilungen aus Iran 1 (1929) 4-16.

Stronach, D., Pasargadae. A report on the excavations conducted by the British Institute of Persian Studies from 1961 to 1963, Clarendon Press, Oxford (1978).

Stronach, D., ‘Anshan and Parsa: early Achaemenid history, art and architecture on the Iranian plateau’, in Mesopotamia and Iran in the Persian Period: conquest and imperialism 539-331 BC, ed. J. Curtis, British Museum Press, London (1997) 35-53.

Ernst Herzfeld Papers, ‘Note Books’, in Freer/Sackler Gallery of Art Archives, Slideshow | /Public_Sets/FS/FSA/FSA_A.06_03.92 (accessed 2024-08-12).

‘Public_Sets’, in Freer/Sackler Gallery of Art Archives, Slideshow | /Public_Sets/FS/FSA/FSA_A.06_02.01.04 (accessed 2024-08-12).

Roaf, M., Sculptures and sculptors at Persepolis, Iran XXI, The British Institute of Persian Studies, London (1983).

Schmidt, E., Persepolis. Structures. Reliefs. Inscriptions, University of Chicago Press, Chicago (1953).

Rehm, E., ‘Die Abklatsche aus Persepolis und Pasargadae von Friedrich Sarre im Museum für Islamische Kunst in Berlin’, Mitteilungen der Deutschen Orient-Gesellschaft zu Berlin 153 (2021) 27-55.

Walser, G., Die Völkerschaften auf den Reliefs von Persepolis, Gebr. Mann, Berlin (1966).

‘Persepolis, Apadana, North Stairs, Tribute Bearers, Sogdians’, in Livius.org − Articles on ancient history, https://www.livius.org/pictures/iran/persepolis/persepolis-apadana/persepolis-apadana-north-stairs/apadana-north-stairs-tribute-bearers-sogdians/ (accessed 2024-05-17).

Gropp, G., ‘Die Darstellung der 23 Völker auf den Reliefs des Apadana von Persepolis’, Iranica Antiqua 154 (2009) 283-359, https://doi.org/10.2143/IA.44.0.2034381.

Herzfeld, E.; Sarre, F., Iranische Felsreliefs. Aufnahmen und Untersuchungen von Denkmälern aus alt- und mittelpersischer Zeit, Wasmuth, Berlin (1910).

Nagel, A., Colors, gilding and painted motifs in Persepolis: approaching the polychromy of Achaemenid Persian architectural sculpture, c. 520-330 BCE, PhD dissertation, Department of History of Art, University of Michigan, Ann Arbor (2010).

Oudbashi, O.; Shekofteh, A.; Fadaei, H., ‘An exploration of a 2500-year-old monument: a reappraisal of the Achaemenian decorative flooring plasters in Persepolis world heritage site (ca. 550-330 BCE)’, Studies in Conservation 68(5) (2022) 491-501, https://doi.org/10.1080/00393630.2022.2062562.

Matson, F., ‘A study of wall plaster, flooring and bitumen’, in Persepolis I: structures, reliefs, inscriptions, ed. E. Schmidt, University of Chicago Press, Chicago (1953) 285-288.

Lafuente, B.; Downs, R. T.; Yang, H.; Stone, N.; Armbruster, T.; Danisi, R. M., ‘The power of databases. The RRUFF project’, Highlights in Mineralogical Crystallography 1 (2015) 25, https://doi.org/10.1515/9783110417104-003.

Bouchard, M.; Smith, D.C., ‘Catalogue of 45 reference Raman spectra of minerals concerning research in art history or archaeology, especially on corroded metals and coloured glass’, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 59(10) (2003) 2247-2266, https://doi.org/10.1016/S1386-1425(03)00069-6.

Bell, I.M.; Clark, R.J.; Gibbs, P.J., ‘Raman spectroscopic library of natural and synthetic pigments (pre-1850 AD)’, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 53(12) (1997) 2159-2179, https://doi.org/10.1016/S1386-1425(97)00140-6.

‘PR4’, in Soprano spectral library, https://soprano.kikirpa.be/index.php?lib=sop&id=PR4_B_785_kikirpa (accessed 2024-04-04).

Scheuermann, W.; Ritter, G. J., ‘Raman spectra of cinnabar (HgS), realgar (As4S4) and orpiment (As2S3)’, Zeitschrift für Naturforschung A 24(3) (1969) 408-411, https://doi.org/10.1515/zna-1969-0317.

de Faria, D. L. A.; Lopes, F. N., ‘Heated goethite and natural hematite: can Raman spectroscopy be used to differentiate them?’ Vibrational Spectroscopy 45(2) (2007) 117-121, https://doi.org/10.1016/j.vibspec.2007.07.003.

Coccato, A.; Jehlicka, J.; Moens, L.; Vandenabeele, P., ‘Raman spectroscopy for the investigation of carbon‐based black pigments’, Journal of Raman Spectroscopy 46(10) (2015) 1003-1015, https://doi.org/10.1002/jrs.4715.

Tomasini, E.P.; Halac, E.B.; Reinoso, M.; Di Liscia, E.J.; Maier, M.S., ‘Micro‐Raman spectroscopy of carbon‐based black pigments’, Journal of Raman Spectroscopy 43(11) (2012) 1671-1675, https://doi.org/10.1002/jrs.4159.

Cuesta, A.; Dhamelincourt, P.; Laureyns, J.; Martinez-Alonso, A.; Tascon, J. M. D., ‘Comparative performance of X-ray diffraction and Raman microprobe techniques for the study of carbon materials’, Journal of Materials Chemistry 8(12) (1998) 2875-2879, https://doi.org/10.1039/A805841E.

de Faria, D. L.; Venâncio Silva, S.; de Oliveira, M. T., ’Raman microspectroscopy of some iron oxides and oxyhydroxides’, Journal of Raman Spectroscopy 28(11) (1997) 873-878, https://doi.org/10.1002/(SICI)1097-4555(199711)28:11<873::AID-JRS177>3.0.CO;2-B.

Oudbashi, O.; Hessari, M.; Shekofteh, A., ‘Minero‐chemical and provenance analysis of Achaemenian lapis lazuli cylinders from Persepolis’, Archaeometry 66(1) (2024) 57-75, https://doi.org/10.1111/arcm.12903.

Amadori, M. L.; Vagnini, M.; Vivani, R.; Anselmi, C.; Chaverdi, A. A.; Callieri, P.; Matin, E.; Mengacci, V., ‘Advances in the characterization of colourful residues unearthed in Persepolis West craft zone using microscopic and spectroscopic techniques’, Microchemical Journal 167 (2021) 106304, https://doi.org/10.1016/j.microc.2021.106304.

Oudbashi, O.; Hessari, M., ‘A “Western” imported technology: an analytical study of Achaemenid Egyptian blue objects’, Journal of Cultural Heritage 47 (2021) 246-256, https://doi.org/10.1016/j.culher.2020.11.001.

Oudbashi, O.; Shekofteh, A.; Eskandari, N., ‘Provenance of the Bronze Age lapis lazuli pieces from the Early Urban Center of Konar Sandal, Jiroft, Southern Iran’, Journal of Archaeological Science: Reports 55 (2024) 104527, https://doi.org/10.1016/j.jasrep.2024.104527.

Chukanov, N. V.; Sapozhnikov, A. N.; Shendrik, R. Y.; Vigasina, M. F.; Steudel, R., ‘Spectroscopic and crystal-chemical features of sodalite-group minerals from gem lazurite deposits’, Minerals 10(11) (2020) 1042, https://doi.org/10.3390/min10111042.

González-Cabrera, M.; Arjonilla, P.; Domínguez-Vidal, A.; Ayora-Cañada, M. J., ‘Natural or synthetic? Simultaneous Raman/luminescence hyperspectral microimaging for the fast distinction of ultramarine pigments’, Dyes and Pigments 178 (2020) 108349, https://doi.org/10.1016/j.dyepig.2020.108349.

Zarkhord, S.; Nemati-Babaylou, A.; Koochakzaei, A., ‘The methodology of Lzurite (Lājavard) making in ancient Persian scientific texts’, Journal for the History of Science 21(2) (2024) 87-114, 10.22059/jihs.2024.374980.371787.

Gettens, R. J., ‘The materials in the wall paintings of Bamiyan, Afghanistan’, Technical Studies in the Field of the Fine Arts 6(3) (1938) 186-193.

Plesters, J., ‘Ultramarine blue, natural and artificial’, Studies in Conservation 11(2) (1966) 62-75, https://doi.org/10.1179/sic.1966.009.

Holakooei, P.; Karimy, A. H., ‘Early Islamic pigments used at the Masjid-i Jame of Fahraj, Iran: a possible use of black plattnerite’, Journal of Archaeological Science 54 (2015) 217-227, https://doi.org/10.1016/j.jas.2014.12.001.

Nagel, A.; Aibéo, C.; Simon, S., ‘New blue surfaces at Persepolis: recent observations on the polychromies of inscribed stone slabs from the Frataraka complex’, in Working on stones in the Achaemenid Persian empire, ed. A. Nagel, J. Thomalsky & Z. Zehbari, Reimer, Berlin (in press).

Bicchieri, M.; Nardone, M.; Russo, P. A.; Sodo, A.; Corsi, M.; Cristoforetti, G.; Palleschi, V.; Salvetti, A.; Tognoni, E., ‘Characterization of azurite and lazurite-based pigments by laser-induced breakdown spectroscopy and micro-Raman spectroscopy’, Spectrochimica Acta Part B: Atomic Spectroscopy 56(6) (2001) 915-922, https://doi.org/10.1016/S0584-8547(01)00228-2.

Colomban, P., ‘Lapis lazuli as an unexpected blue pigment in Iranian Lâjvardina ceramics’, Journal of Raman Spectroscopy 34(6) (2003) 420-423, https://doi.org/10.1002/jrs.1014.

Holakooei, P.; de Lapérouse, J. F.; Rugiadi, M.; Carò, F., ‘Early Islamic pigments at Nishapur, north-eastern Iran: studies on the painted fragments preserved at The Metropolitan Museum of Art’, Archaeological and Anthropological Sciences 10 (2018) 175-195, https://doi.org/10.1007/s12520-016-0347-7.

Osticioli, I. A.; Mendes, N. F.; Nevin, A.; Gil, F. P.; Becucci, M.; Castellucci, E. M., ‘Analysis of natural and artificial ultramarine blue pigments using laser-induced breakdown and pulsed Raman spectroscopy, statistical analysis and light microscopy’, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 73(3) (2009) 525-31, https://doi.org/10.1016/j.saa.2008.11.028.

Favaro, M.; Guastoni, A.; Marini, F.; Bianchin, S.; Gambirasi, A., ‘Characterization of lapis lazuli and corresponding purified pigments for a provenance study of ultramarine pigments used in works of art’, Analytical and Bioanalytical Chemistry 402 (2012) 2195-2208, https://doi.org/10.1007/s00216-011-5645-4.

Aloiz, E.; J. Douglas; A. Nagel, ‘Painted plaster and glazed brick fragments from Achaemenid Pasargadae and Persepolis, Iran’, Heritage Science 4(3) (2016), https://doi.org/10.1186/s40494-016-0072-7.

Hanesch, M., ‘Raman spectroscopy of iron oxides and (oxy) hydroxides at low laser power and possible applications in environmental magnetic studies’, Geophysical Journal International 177(3) (2009) 941-948, https://doi.org/10.1111/j.1365-246X.2009.04122.x.

Momenzadeh, M.; Nezafati, N.; Sarraf, M. R.; Shabani, K., ‘Ancient gold-mercury mining in the Takht-e Soleyman area, Northwest Iran’, Metalla 22(2) (2016) 147-168, https://doi.org/10.46586/metalla.v22.2016.i2.147-168.

Shekofteh, A.; Molina, E.; Arizzi, A.; Cultrone, G.; Ahmadi, H.; Yazdi, M., ‘Characterization and damage assessment of stones used in the Pasargadae World Heritage Site, Achaemenian period’, International Journal of Architectural Heritage 13(4) (2019) 521-536, https://doi.org/10.1080/15583058.2018.1436728.

Gettens, R.; Feller, R.; Chase, W., ‘Vermilion and cinnabar’, Studies in Conservation 17 (1972) 45-69, https://doi.org/10.1179/sic.1972.006.

Gotoshia, S. V.; Gotoshia, L. V., ‘Laser Raman and resonance Raman spectroscopies of natural semiconductor mineral cinnabar, α-HgS, from various mines’, Journal of Physics D: Applied Physics 41(11) (2008) 115406, https://doi.org/10.1088/0022-3727/41/11/115406 .

Frietsch, R., The relationship between magnetite and hematite in the iron ores of the Kiruna type and some other iron ore types, Sveriges Geologiska Undersökning, Uppsala (1967).