Caracterização das ligas metálicas de coretos alemães do início do século XX expostos ao clima amazónico de Belém, Brasil

Autores

  • Thainá Thais Silva Oliveira Federal University of Pará, Cultural Heritage Sciences Graduate Program, Architecture and Urban Planning Graduate Program, Castilhos França Blvd. (w/o no.), 66010-060 Belém, Pará, Brazil https://orcid.org/0000-0002-4973-1723
  • Flávia Olegário Palácios Federal University of Pará, Cultural Heritage Sciences Graduate Program, Architecture and Urban Planning Graduate Program, Castilhos França Blvd. (w/o no.), 66010-060 Belém, Pará, Brazil; Federal University of Pará, Conservation and Restoration Faculty, Castilhos França Blvd. (w/o no.), 66010-060 Belém, Pará, Brazil https://orcid.org/0000-0003-2818-2507

DOI:

https://doi.org/10.14568/cp35869

Palavras-chave:

Ligas de ferro, Ferro fundido, Produtos de corrosão, Arquitetura do ferro, Património arquitetónico

Resumo

O progresso da indústria do ferro nos séculos XVIII e XIX deixou um património edificado notável em países não europeus, como o Brasil. Em particular, a cidade de Belém possui cinco coretos metálicos importados da Alemanha e instalados na Praça Batista Campos, em 1903. Apesar do seu significado histórico, arquitetónico, técnico e social, estes coretos estão sujeitos a uma gradual deterioração, descaracterização e ações de manutenção inadequadas resultantes da falta de conhecimento. Este artigo pretende caracterizar as ligas metálicas e os produtos de corrosão destes coretos. Foram realizadas análises por microscopia eletrónica de varrimento, espectroscopia de raios X por dispersão em energia e difração de raios X em diferentes componentes construtivos. Os resultados mostraram o uso abundante de ferro fundido cinza nodular, a aplicação de aço, o tipo de corrosão e o estado de conservação dos revestimentos. Essas informações ampliam o conhecimento sobre a utilização de ligas ferrosas e sua corrosão em edifícios históricos.

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Referências

Lister, R., Decorative cast ironwork in Great Britain, G. Bell and Sons, London, (1960).

Silva, G. G. da, Arquitetura do ferro no Brasil, Nobel, São Paulo (1986).

Higgs, M., ‘The exported iron buildings of Andrew Handyside & Co. of Derby’, Journal of the Society of Architectural Historians 29(2) (1970) 175-180, https://doi.org/10.2307/988651.

Gomes, G., ‘Artistic intentions in iron architecture’, The Journal of Decorative and Propaganda Arts 21 (1995) 86-107, https://doi.org/10.2307/1504133.

Sarges, M. N., Belém: riquezas produzindo a belle époque (1870-1912), 3rd ed., Editora Paka-Tatu, Belém (2010).

Coelho, G. M., ‘Belém e a belle époque da borracha’, Revista Observatório 2(5) (2016) 32-56, https://doi.org/10.20873/uft.2447-4266.2016v2n5p32.

Lemos, A. J. de, ‘O município de Belém. Relatório apresentado ao Conselho Municipal de Belém capital do Pará referente à 1903’, s.n., Belém (1904), https://obrasraras.fcp.pa.gov.br/publication/file/relatorios/lemos/omunicipiodebelemrelatoriolemos1904referentea1903/ (accessed 2023-10-06).

Oliveira, T. T. S.; Palácios, F. O., ‘History and architectural characteristics of the iron bandstands in Belém, Pará’, PARC Pesquisa em Arquitetura e Construção 14 (2023) e023016, https://doi.org/10.20396/parc.v14i00.8670968.

Sembrat, J.; Rabinowitz, M.; Bello, J., ‘Investigating and restoring decorative finishes on architectural metals’, Journal of Architectural Conservation 18(3) (2012) 27-51, https://doi.org/10.1080/13556207.2012.10785117.

de Bouw, M.; Wouters, I.; Vereecken, J.; Lauriks, L., ‘Iron and steel varieties in building industry between 1860 and 1914 – a complex and confusing situation resolved, Construction and Building Materials 23(8) (2009) 2775-2787, https://doi.org/10.1016/j.conbuildmat.2009.03.009.

de Ruggiero, A. C; Calzolari, L.; Soffritti, C.; Varone, A., Garagnani, G. L., ‘Cast iron metalworks in European urban furniture dating back to the 19th and the early 20th centuries’, Materials Science Forum 941 (2018) 663-667, https://doi.org/10.4028/www.scientific.net/MSF.941.663.

Scott, D. A., ‘The use of metallographic and metallurgical investigation methods in the preservation of metallic heritage artefacts’, in Corrosion and Conservation of Cultural Heritage Metallic Artefact, eds. P. Dillmann, D. Watkinson, E. Angelini and A. Adriaens, Woodhead Publishing, Cambridge (2013) 1-5, https://doi.org/10.1533/9781782421573.2.82.

Dillmann, P.; Watkinson, D.; Angelini, E., Adriaens, A., ‘Introduction: conservation versus laboratory investigation in the preservation of metallic heritage artefacts, in Corrosion and Conservation of Cultural Heritage Metallic Artefacts, eds. P. Dillmann, D. Watkinson, E. Angelini and A. Adriaens, Woodhead Publishing, Cambridge (2013) 82-99, https://doi.org/10.1533/9781782421573.1.

Goldstein, J. I.; Newbury, D.E.; Michael, J. R.; Ritchie, N. W. M.; Scott, J. H. J.; Joy, D. C., ‘SEM image interpretation’, in Scanning Electron Microscopy and X-Ray Microanalysis, eds. J. I. Goldstein, D. E. Newbury, J. R. Michael, N. W. M. Ritchie, J. H. J. Scott and D. C. Joy, Springer, New York (2018) 111-121, https://doi.org/10.1007/978-1-4939-6676-9_7.

Gimeno Adelantado, J. V.; Ferrer Eres, M. A.; Valle Algarra, F. M.; Peris Vicente, J.; Bosch Reig, F., ‘Analytical study by SEM/EDX and metallographic techniques of materials used in the iron production process during the Iberian period’, Talanta 60(5) (2003) 895-910, https://doi.org/10.1016/S0039-9140(03)00152-8.

Colpaert, H., Metalografia dos Produtos Siderúrgicos Comuns, Blucher, São Paulo (2008).

Singhal, P.; Saxena, K. K., ‘Effect of silicon addition on microstructure and mechanical properties of grey cast iron: an overview’, Materials Today: Proceedings 26 (2020) 1393-1401, https://doi.org/10.1016/j.matpr.2020.02.281.

Srivastava, R.; Singh, B.; Saxena, K. K., ‘Influence of S and Mn on mechanical properties and microstructure of grey cast iron: an overview’, Materials Today: Proceedings 26 (2020) 2770-2775, https://doi.org/10.1016/j.matpr.2020.02.577.

Hœrlé, S.; Mazaudier, F., Dillmann, P. H.; Santarini, G., ‘Advances in understanding atmospheric corrosion of iron. II. Mechanistic modelling of wet–dry cycles’, Corrosion Science 46(6) (2004) 1431-1465, https://doi.org/10.1016/j.corsci.2003.09.028.

Kreislova, K.; Knotkova, D.; Geiplova, H., ‘Atmospheric corrosion of historical industrial structures’, in Corrosion and Conservation of Cultural Heritage Metallic Artefacts, eds. P. Dillmann, D. Watkinson, E. Angelini and A. Adriaens, Woodhead Publishing, Cambridge (2013) 311-343, https://doi.org/10.1533/9781782421573.3.311.

Soffritti, C.; Calzolari, L.; Balbo, A.; Zanotto, F.; Monticelli, C.; Ospitali, A.; Garagnani, G. L., ‘Conservation state of cast iron metalworks in European street furniture’, The European Physical Journal Plus 134(9) (2019) 424, https://doi.org/10.1140/epjp/i2019-12944-y.

Durand-Charre, M., Microstructure of steels and cast irons, Springer Berlin, Heidelberg, (2004), https://doi.org/10.1007/978-3-662-08729-9.

Rundman, K. D.; Iacoviello, F., ‘Cast irons’, in Cast irons, in Reference Module in Materials Science and Materials Engineering, Elsevier, Oxford (2016) 1003-1010, https://doi.org/10.1016/B978-0-12-803581-8.09803-9.

Iacoviello, F.; di Cocco, V.; Favaro, G., ‘Pearlitic ductile cast iron: mechanical properties gradient analysis in graphite elements’, Procedia Structural Integrity 9 (2018) 9-15, https://doi.org/10.1016/j.prostr.2018.06.004.

Walker, R., ‘The production, microstructure, and properties of wrought iron’, Journal of Chemical Education 79 (2002) 443, https://doi.org/10.1021/ed079p443.

O'Sullivan, M.; Swailes, T., ‘A study of historical test data for better informed assessment of wrought iron structures’, International Journal of Architectural Heritage 3(4) (2009) 260-275, https://doi.org/10.1080/15583050902802337.

di Lorenzo, G.; Formisano, A.; Terracciano, G., Landolfo, R., ‘Iron alloys and structural steels from XIX century until today: evolution of mechanical properties and proposal of a rapid identification method’, Construction and Building Materials 302 (2021) 124132, https://doi.org/10.1016/j.conbuildmat.2021.124132.

Källbom, Arja; Almevik, Gunnar, ‘Maintenance of painted steel-sheet roofs on historical buildings in Sweden’, International Journal of Architectural Heritage 16(4) (2022) 538-552, https://doi.org/10.1080/15583058.2020.1808910.

Gerengi, Husnu; Solomon, Moses M.; Maraslı, Muhammed; Kohen, Beni B., ‘A comparative analysis of the corrosion characteristics of electro-galvanized steel coated with epoxy zinc-free and zinc-rich coatings in 5 % NaCl’, Journal of Adhesion Science and Technology 37(20) (2023) 2795-2806, https://doi.org/10.1080/01694243.2022.2123603.

Torraca, G., Lectures on materials science for architectural conservation, The Getty Conservation Institute, Los Angeles (2009).

Palácios, F. O.; Angélica, R. S.; Sanjad, T. A. B. C., ‘The metal alloys from the XIX century and weathering action in the Mercado do Ver-o-Peso building, northern Brazil: identification with the usage of laboratory analysis’, Materials Characterization 96 (2014), 225-233, https://doi.org/10.1016/j.matchar.2014.08.004.

Oliveira, T. T. S.; Palácios, F. O., ‘Os coretos de ferro dos séculos XIX e XX em Belém (PA): transformações e reconhecimento de significados e valores’, Revista CPC 18(35) (2023) 140-172, https://doi.org/10.11606/issn.1980-4466.v18i35p140-172.

Tewary, U.; Paul, D.; Mehtani, H. K.; Bhagavath, S.; Alankar, A.; Mohapatra, G.; Sahay, S. S.; Panwar, A. S.; Karagadde, S.; Samajdar, I., ‘The origin of graphite morphology in cast iron’, Acta Materialia 226 (2022) 117660, https://doi.org/10.1016/j.actamat.2022.117660.

McCowan, C. N.; Siewert, T. A.; McColskey, J. D.; Hildebrand, K.; Olson, D. L., ‘United States Capitol dome: characterization of cast and wrought materials’, Materials Characterization 62 (2011) 807-816, https://doi.org/10.1016/j.matchar.2011.05.002.

Soffritti, C.; Calzolari, L.; Balbo, A.; Zanotto, F.; Monticelli, C.; Fortini, A.; Garagnani, G. L., ‘Study of the conservation state of European street furniture in painted cast irons’, La Metallurgia Italiana 4 (2018) 5-16, http://www.aimnet.it/la_metallurgia_italiana/2018/aprile/soffritti.pdf (accessed 2022-12-15).

Soffritti, C.; Calzolari, L.; Pepi, S.; Fortini, A.; Merlin, M.; Garagnani, G. L., ‘Metallurgical and statistical approaches to the study of cast iron street furniture’, Metallurgical and Materials Transactions A 52 (2021) 1127-1141, https://doi.org/10.1007/s11661-021-06135-6.

Stefanescu, D. M., ‘A history of cast iron’, in Handbook ASM. Volume 1A – Cast iron science and technology, ed. D. M. Stefanescu, ASM International, Ohio (2017) 3-11, https://doi.org/10.31399/asm.hb.v01a.a0006320.

Bramaramba, V.; Behera, R. K.; Saurabh, S.; Sen, S., ‘Quantitative phase analysis: it’s role in characterization of spheroidal graphite iron’, Materials Today: Proceedings 27 (2020) 1728-1732, https://doi.org/10.1016/j.matpr.2020.03.649.

Lacaze, J.; Connétable, D., Castro-Román, M. J., ‘Effects of impurities on graphite shape during solidification of spheroidal graphite cast irons’, Materialia 8 (2019) 100471, https://doi.org/10.1016/j.mtla.2019.100471.

Costa, Marcondes L. da; Sanjad, Thais A. B. C.; Paiva, Rosildo S., ‘The mineralogy and chemistry of the German and Portuguese tiles used to face a historic building in the Amazon region and their natural susceptibility to tropical weathering’, Acta Amazonica 43(3) (2013) 323-330, https://doi.org/10.1590/S0044-59672013000300008.

Sanjad, Thais A.B.C.; Costa, Marcondes L. da; Paiva, Rosildo S.; Palácios, Flávia Olegário, ‘Ação microbiológica nos azulejos históricos das fachadas de Belém, região amazônica’, PÓS: Revista do Programa de Pós-graduação em Artes da EBA/UFMG 4(8) (2014) 124-133, https://periodicos.ufmg.br/index.php/revistapos/article/view/15484.

Sykora, Miroslav; Kreislova, Katerina; Pokorny, Petr, ‘Corrosion of historic grey cast irons: indicative rates, significance, and protection’, International Journal of Computational Methods and Experimental Measurements 8(2) (2020) 162-174, https://doi.org/10.2495/CMEM-V8-N2-162-174.

The sampling areas of the covered architectural elements, guardrail

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Publicado

2025-01-04

Como Citar

Oliveira, T. T. S. ., & Palácios, F. O. (2025). Caracterização das ligas metálicas de coretos alemães do início do século XX expostos ao clima amazónico de Belém, Brasil. Conservar Património. https://doi.org/10.14568/cp35869

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